Исследования химии

Наряду с исследованиями химии чеснока успешно продвигалось и изучение лука. В 1961 г. финский биохимик Виртанен (который в 1945 г. получил Нобелевскую премию по химии) показал, что в луке содержится транс-( + )-S-( 1 -пропенил)-Ь-цистеин- сульфокснд — структурный изомер аллиина (см. нижний рисунок на с. 60). По химическому составу оба соединения одинаковы, однако структура у них разная, а именно: различается ориентация атомов при двойной связи, которая, как указывает цифра 1 в названии, находится непосредственно у атома серы. Транс-( + )-S-(l-npo- пенил)-Ь-цистеинсульфоксид является предшественником лакриматорно- го фактора — вещества, вызывающего слезы (ЛФ). Фермент аллиназа лука превращает предшественник в ЛФ.

Химическая формула лакрима- торного фактора C3H6SO. Этой формуле отвечают более 50 соединений с различной химической структурой. Виртанен постулировал, что истинная структура лакрима- торного фактора соответствует формуле СН3СН = CHS(0)H, а не

CH,CH = CHS—О — H; во втором случае атом кислорода расположен в основной цепи углеродного скелета молекулы. (Оба соединения называются «троне-1-пропеисульфеновая кислота».) Одновременно У. Уилкинс, в то время студент Корнеллского университета, предложил другую структурную формулу лакриматор- ного фактора — С2Н5СН = SO; такое соединение называется S-окись про- пантиоальдегида. Через 10 лет, в 1971 г. М. Бролниц и Дж. Паскаль из International Flavors and Fragrances Company (Юнион-Бич, шт. Нью- Джерси) подтвердили предположение Уилкинса.

Итак, в чесноке фермент аллиназа превращает аллиин в сильно пахнущее вещество — аллицин. В луке такой же фермент превращает предшественник лакриматорного фактора в лакриматорный фактор. Однако ал- линазы чеснока и лука действуют не только на эти молекулы, но и на некоторые другие; в таких случаях химики говорят, что фермент обладает широкой субстратной специфичностью. Субстратами аллиназ являются серу- содержащие соединения, которые синтезируются в чесноке и луке различными путями, но исходным веществом всегда служит серу содержащая аминокислота цистеин. Под действием аллиназ образуются разные сульфеновые кислоты, общая формула которых RSOH, где R может быть аллилом СН2=СНСН2, 1-пропени- лом СН3 — СН = СН, метилом СН3 или пропилом С3Н7. В качестве побочных продуктов в этих реакциях получаются пируват CHjC(0)C0^" и аммиак NHj.

 

238 Comments

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  104. Exactly! At the most basic level I’d say that psychology focuses more on the past, and NLP focuses more on the future — yet to your point, uses subtle language to influence the individuals self-evaluation process. E.g. if they are anxious, they might be asked “at what point do you decide to be anxious” (reinforcing the choice being within their control). I believe it also seeks to use the subconscious more – almost literally like ‘reprogramming’ ones perception (which obviously could be controversial in some cases). Anyway, it’s definitely an interesting subject matter! Take care!!

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  134. Shiver me timbers, them’s some great information.

  135. Beautiful recipe, Mary! I so agree about putting the veggies and the meat on separate kabobs. Strangely, most people do not do this. It is not hard to figure out. They do look prettier on the skewers in different colors, but they just don't cook correctly.

  136. That’s going to make things a lot easier from here on out.

  137. Bonjour Gaëtan,Ah ! colorant pelure d’oignon, je n’y avais pas pensé… Aujourd’hui E163V (chou rouge) et E162 (betterave), c’était plus poétique.Voyez-vous, rien qu’en lisant « …dans le Valois de mon enfance », l’envie me prend de rêver. C’est très engageant.Merci cher Gaëtan et laissons notre enfance vagabonder dans notre présent pour nous livrer ses plus beaux tableaux. Nos Renoir, intemporels aussi.

  138. Merci vinvin, effectivement, ça ne laisse pas de marbre….Et je doute que cela soit un fake.Ayant moi meme coulé grace à nos amis les banquiers il y a quelques années, je comprends ce qu’il dit….ça fout les boules….

  139. Brian this brings up another point that I think is often overlooked. We know that Elohim is a God and that Jehovah is a god but what is not often mentioned is that Michel is also a God. We know this because all 3 have the Keys of creation. It is possible for one to obtain at least a lesser form of godhod without a physical body.

  140. I’m impressed! You’ve managed the almost impossible.

  141. Hi, i think that i saw you visited my website thus i came to “return the favor”.I am trying to find things to improve my web site!I suppose its ok to use some of your ideas!!

  142. Bonsoir,La monographie de Gorz, “L’immatériel”, qui m’a incité à reconsidérer ma position au sein du système politique et économique qui l’entoure et sous-tend la société d’information. Personnellement, J’ai trouvé plus facile de l’analyse de Negri et le marxiste italien qui en parlent “usine sociale”. Peut-être parce que la langue est plus moderne, Cela ne signifie pas que la gauche rejette la littérature. Le contraire. Excellent effort que vous!

  143. C’est pas Phau, le Mayer ne gagne pas à tous les coups. Mannarino est bouchée, je me suis mouché, Beck c’est dégueulasse.A bientôt les gars…

  144. It’s good to get a fresh way of looking at it.

  145. It’s much easier to understand when you put it that way!

  146. Le plus long que j'ai traduit, c'était le tome 11 d'AB. 3 mois, 1100 feuillets, j'ai cru que je ne le finirais jamais. Mais bien entendu, tout est une question de volume du texte (et un peu de sa difficulté, aussi!)

  147. Marie Angebonjouroui C'est dommage pour ton arbre et tes noisettesle plaisir d'en ramasser oui je te comprends tu sais et ensuite de les avalerJ'adore les noisettes et tu ne vois pas des écureuils!!!!!!Merci pour ta mante religieuse elle est si belleBISOU

  148. Chi Fi still waiting for you to go steal an Alpaca for meat, come on it right down the road.Maybe you could shoot a game of hoops , go ice skating, catch a movie , go horse back ridding, take a swim before you do the deed & I’m sure I missed something. Just regular folks you know.

  149. You can simply see the expertise inside the work a person write. The world hopes for more passionate writers like you who are not afraid to state how they believe. Always adhere to your center.

  150. I do accept as true with all the ideas you have introduced for your post. They’re really convincing and can certainly work. Still, the posts are very quick for newbies. Could you please extend them a little from next time? Thank you for the post.

  151. up sites with the intention of using…them as starting points for their services.let me explain. someone might set up a membership site with drip content, with featured content areas, with videos, with menus, all things that might have taken an hour or longer to set up. when…

  152. Hoje mesmo vi recusar uma oferta de emprego a receber 500€ limpos mais 3% de comissão nas vendas.Argumento: Ganho o mesmo no Fundo de Desemprego e não tenho que me preocupar com nada!Assina: mais um otário

  153. Doch – weil iTunes oder Amazon nur kastrierten Müll verkaufen. Aus ner CD kannst du wenigstens Apple Lossless oder FLAC rauskitzeln. Oder man saugt sich alles illegal, was deiner Argumentation der Normalzugang für Lossless wäre …

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  155. saya sedang menyusun ebook masalh itu. Jadi tunggu aja ya!kalo udah launching, aku di kabarin ya!!! pengen lebih banyak tau juga nih March 6, 2008 at 8:34 pmReply

  156. And to think I was going to talk to someone in person about this.

  157. NMD, I didnt comment yesterday but Bravo (no pun intended) on giving Caroline the Gold Star Award. She has really been getting the message out about Sandy and working very hard. She was tweeting until midnight. My only question is, where was Wacky Jacky when her optimal tweeting skills were needed? She loves twitter so much, I wonder if she even bothered tweeting to help other people? I ask all of these questions because her tweets are protected.

  158. Your post has lifted the level of debate

  159. I STILL hate fourth wall jokesWhereas I am still a sucker for fourth-wall breakage and any other fashion in which a creative work might refer to itself.   1 likes

  160. I’m truly enjoying the design and layout of your website. It’s a very easy on the eyes which makes it much more enjoyable for me to come here and visit more often. Did you hire out a designer to create your theme? Fantastic work!

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  162. Very thorough indeed. I am looking forward to deploying some Leopard servers to replace our Panther and Tiger servers (oh my!). I am also looking forward to testing Leopard before I deploy it. If only.

  163. We too enjoy Cockenoe for it’s bird and plant life. Thank you for taking away the bottles, cans and debris, we will bring a garbage bag next time and do likewise. I think some of it may wash up from other locations too?Great photos too.The Great Race sounds like a great idea, – so garbage picking up on Cockenoe is a tradition!

  164. I just want to say I’m beginner to blogs and truly loved this blog site. Likely I’m going to bookmark your site . You absolutely have fabulous posts. Cheers for revealing your blog.

  165. avessi io quel fisico ke ti ritrovi… starei già a fare il pornoattore credimi!peccato per lo sfondo, sarebbe stata una foto fantastica… però mi offendo… a me non hai mai inviato una rikiesta del genere… uff!mopat

  166. jo soličko sem zvládl akorát na kotelnÄ›, ale pokud budeÅ¡ mít zájem o kompanÄ›ra, tak dej vÄ›dÄ›t, rád se podívám i ven….vlku s propagandou už chápu….ale jiná vÄ›c, pokud sám Hýsek Å™ek, že tu svou cestu dotáh jen na dvÄ› délky (dnes slaňák Náskoku a nástup Holubáče), tak proč tvrdíš, že ten průlez tou jeskyní a výlez z okovů patří k tomu????asu

  167. Wow! Talk about a posting knocking my socks off!

  168. And on and on doth CF shuffle.Some hooded 'necks could be leading him to a pine tree with a noose around his neck and he'll still be yapping about black ghetto thugs.

  169. To Rudeboi19 “i would have done exactly as Dizzee did and played Paxman at his own game”Dizzee play Paxman? PAXMAN PLAYED DIZZEE!!! Those questions were obviously designed to catch Dizzee out and he fell for the bait… WAKE UP and see beyond the limits of ‘road mentality’.

  170. Further evidence of the great way perfumistas "click" on international blind sniffing dates! Your sampling session sounds like a lot of fun (not least the Kir and the PG Christmas purchase…. : – 0 ).

  171. Your website has to be the electronic Swiss army knife for this topic.

  172. 29/05/2010 – 11:51amsobre mourinho, me está empezando a caer bien, después de leer las entrevistas q le hizo AS y tras declinar esas chorrapresentaciones del verano pasado como si el bernabeu fuera un circo, quiere una presentación con rueda de prensa seria,no subirse a una tarima y gritar “1-2-3 hala madrid!”

  173. Yes. The footage is from season one but clips are from many episodes not just one. Through out the season really, can’t really name the ones. sorry.

  174. hey ab, didn't i see you posting on you tube, you broadcast from a toilet or something? yup, it was you, a white man with an old voice, full of shit, lmao.

  175. Szerintem ettől függetlenül még bejelenthetik jövő héten, hogy mégis inkább Oroszországban dúsítják az uránjukat. Az utáni héten pedig, hogy mégis inkább otthon. Aztán mégis az oroszoknál. Aztán előbb-utóbb csak kész lesz az elegendő mennyiség, akkor legalább véget ér ez a színjáték.Tetszik / Egyetértek: 0 Az értékeléshez be kell

  176. I am exploring the Internet as I never have berofe. I have more time since I reitred. I can see that there is a rich diversity in the blogs I am reading and I am trying to leave some comment whereever I visit. You have made your blog more interesting than most that I read. Thanks for that. I not only read and comment on the blogs of others but I now have my own blog and my own website. My email and site are included with this post. I think it is ok that I incuded them since there seems to be a place to do that. Hope so anyway. TheVeryBest2You 13 9

  177. No cóż… U mnie Firefox 3 nie traktuje ciÄ…gu “poczta.o2.pl” jako adresu internetowego – klawisz Enter nie dziaÅ‚a, nic siÄ™ nie dzieje. Tak samo nie reaguje na komendy YubNub. To bug, czy ficzer? :-P

  178. Four score and seven minutes ago, I read a sweet article. Lol thanks

  179. Life is short, and this article saved valuable time on this Earth.

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  181. 13/11/2012 at 05:42Once I originally commented I clicked the -Notify me when new comments are added- checkbox and now each time a comment is added I get four emails with the identical comment. Is there any manner you’ll be able to remove me from that service? Thanks! Log in to Reply

  182. The next time I read a blog, I hope that it doesnt disappoint me as much as this one. I mean, I know it was my choice to read, but I actually thought youd have something interesting to say. All I hear is a bunch of whining about something that you could fix if you werent too busy looking for attention.

  183. Hosting a fundraiser = paying a cover and donating a bagful of old clothes to drink comped booze. Sorry, but there are better ways to help. “Feel free to RSVP to the event on Facebook. We’re expecting a great crowd, copious amounts of tequila, tunes spun by Bricolage, and that warm, fuzzy feeling you get when you know you’re helping someone (or maybe that’s the margaritas.)”

  184. Going to do a bit of a cheat – I made card for the CCT challenge but it also fits the challenge (and I think its beter than the one I made for this challenge LOL!!)Thanks for looking,Cathy xx

  185. This is what I call a "gratitude attack". They're occurring all over the place, and in my most unscientific poll I've concluded it's because of the Lord. How precious!Blessings, Kathleen

  186. Stets zu Diensten, liebe Black! Aber … soweit ich weiß hast Du doch mehr als einen guten Grund, der Dich in den nächsten Wochen/Monaten auch in den Pott führen wird … da ließe sich womöglich auch ein Theaterbesuch einplanen, oder?

  187. How are the views of Rodney Hide and ACT on the issue of dedicated Maori seats on the Auckland Super City council racist exactly?Isn't Racism is when you discriminate against some person because of their race as opposed to not ensuring you have guarranteed representation? ACT's views might be culturally insensitive and even against the spirit of the Treaty of Waitangi but I would hardly call them racist. If they were then the fact that Pacific Islanders and Asians are not being guarranteed representation is also racist.

  188. Nice cars, nice people. Enjoyed seeing Pertanos Mazda, Mike’s Hakosuka, the AE86s, and those squeaky clean 510s. Thanks for hosting IMG and the food was tasty too.

  189. Hola Sergio:¡¿Qué demonios?! jajajaja estas bien loco XD jajajaja y te comparas con el video mas gracioso del Birdman jajajaYa deja tu estado emo, no te deja nada buenoBesos

  190. All that and… if I buy a physical book and other members of my family want to read it, they don’t buy separate copies. It is normal use of a book to share it. Kindle does have a never-promoted provision for lending books but it has to be turned on, book-by-book, by the publisher and it almost never is.

  191. ik hoef niet aft te vallen ik ben van nature een slanke type , maar ik promoot gezond etenjaja fruit is goed erg goed ook. maar ik heb gehoord dat in druiven veel suiker zitten.en dat je ook niet te veel er van moet eten .ik kom net van de gym, ben erg te vreden met mijn body.Een klein beetje hangende bui die is ook ge reduceerd, ok groetjes .

  192. Exatamente, não é exagerado. É fiel ao livro. Outra observação: A Carrie não é piromaníaca, o dom que ela tem é o da telecinésia.

  193. Great! I've been using Hydroxypropyl Starch Phosphate in this one face cleanser I really like, and I've put double the max in it and it still won't thicken. Gonna give this a try asap. Thank you for clearing that up and sharing your experience with this and all ingredients.

  194. Oh yes Catherine! That bit when you're galloping along, finding it hard to type quickly enough. Saying it out loud wouldn't be fast enough either. And sometimes it's rubbish, but more often than not, when it flies I think it has something important to say about the story. I like to think so anyway!Good post Nicky. Thanks!

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  196. Wow that was odd. I just wrote an very long comment but after Iclicked submit my comment didn’t appear. Grrrr… well I’m not writingall that over again. Anyway, just wanted to say great blog!

  197. People are yours alright! . We at the very least should get these folks stealing photos to start out running a blog! They almost certainly just did a picture lookup and grabbed them. They search great however!

  198. Hi Kit! First off, I love your name. Secondly, thanks for following me! As you can see, it's a work in progress. And lastly, your blog is fantastic! The photos are so sweet and those vintage dresses are incredibly fun. I'm sure your shop will be a hit! Following back, K

  199. Aw, this was a really great publish. In concept I’d like to publish like this also – taking time and genuine energy to make an excellent write-up… but what can I say… I procrastinate alot and never appear to get some thing carried out.

  200. Le phénomène que tu décris n’est en rien la fin du modèle anglo-saxon, mais la mondialisation de ce modèle à l’ensemble de la planète. Que le centre de gravité évolue, c’est tout à fait normal. Les civilisations vont toujours d’est en ouest. : Asie Mineure puis Grèce, Italie, France, Angleterre, Etats-Unis, Japon, Chine. Tout cela est parfaitement normal.Ce que je dis, c’est qu’il n’y a aucun modèle économique qui émerge en contre-modèle du modèle capitaliste anglo-saxon.Â

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