Исследования химии

Наряду с исследованиями химии чеснока успешно продвигалось и изучение лука. В 1961 г. финский биохимик Виртанен (который в 1945 г. получил Нобелевскую премию по химии) показал, что в луке содержится транс-( + )-S-( 1 -пропенил)-Ь-цистеин- сульфокснд — структурный изомер аллиина (см. нижний рисунок на с. 60). По химическому составу оба соединения одинаковы, однако структура у них разная, а именно: различается ориентация атомов при двойной связи, которая, как указывает цифра 1 в названии, находится непосредственно у атома серы. Транс-( + )-S-(l-npo- пенил)-Ь-цистеинсульфоксид является предшественником лакриматорно- го фактора — вещества, вызывающего слезы (ЛФ). Фермент аллиназа лука превращает предшественник в ЛФ.

Химическая формула лакрима- торного фактора C3H6SO. Этой формуле отвечают более 50 соединений с различной химической структурой. Виртанен постулировал, что истинная структура лакрима- торного фактора соответствует формуле СН3СН = CHS(0)H, а не

CH,CH = CHS—О — H; во втором случае атом кислорода расположен в основной цепи углеродного скелета молекулы. (Оба соединения называются «троне-1-пропеисульфеновая кислота».) Одновременно У. Уилкинс, в то время студент Корнеллского университета, предложил другую структурную формулу лакриматор- ного фактора — С2Н5СН = SO; такое соединение называется S-окись про- пантиоальдегида. Через 10 лет, в 1971 г. М. Бролниц и Дж. Паскаль из International Flavors and Fragrances Company (Юнион-Бич, шт. Нью- Джерси) подтвердили предположение Уилкинса.

Итак, в чесноке фермент аллиназа превращает аллиин в сильно пахнущее вещество — аллицин. В луке такой же фермент превращает предшественник лакриматорного фактора в лакриматорный фактор. Однако ал- линазы чеснока и лука действуют не только на эти молекулы, но и на некоторые другие; в таких случаях химики говорят, что фермент обладает широкой субстратной специфичностью. Субстратами аллиназ являются серу- содержащие соединения, которые синтезируются в чесноке и луке различными путями, но исходным веществом всегда служит серу содержащая аминокислота цистеин. Под действием аллиназ образуются разные сульфеновые кислоты, общая формула которых RSOH, где R может быть аллилом СН2=СНСН2, 1-пропени- лом СН3 — СН = СН, метилом СН3 или пропилом С3Н7. В качестве побочных продуктов в этих реакциях получаются пируват CHjC(0)C0^" и аммиак NHj.



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  3. Yay! Enjoy!I’m actually in the opposite mode a bit – lots of energy and no where to apply it currently. But maybe you can cherish video games, pedicures and reading in the sun more when you’re not totally burnt out.

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  8. All you have to know about Joseph Romm is that he claims that nuclear fission is unaffordable because we spent nearly $100 billion on it whereas «renewable» energy is cheap because it has a predicted price tag of only pennies per day per household.When you do the arithmetic, it turns out that the cost of nukes is also only pennies per day per household and that’s a fact, not a prediction.I think it’s illegal to use Romm’s kind of comparison to sell something financial, but energy policy has different standards.

  9. That’s not just logic. That’s really sensible.

  10. Phenomenal breakdown of the topic, you should write for me too!

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  13. Lo que pasa es que si se elimina el roaming se da pie a la competencia y es mejor que los mercados sigan siendo monopolistas para joder al usuario todo lo que quieran. Son los gobiernos en favor del pueblo los que han hablado, si a las telcos no les gusta pueden irse a laburar a china aver que tal les va.

  14. Normally I’m against killing but this article slaughtered my ignorance.

  15. I almost never leave a response, but I browsed a few of the responses on Brazil, The Next Big Thing? | AIESEC Simon Fraser University – The Blog. I do have a few questions for you if it’s okay. Could it be simply me or do some of the remarks look as if they are left by brain dead people? And, if you are writing at other online sites, I’d like to follow anything new you have to post. Would you make a list of the complete urls of all your public pages like your twitter feed, Facebook page or linkedin profile?

  16. If your articles are always this helpful, «I’ll be back.»

  17. BS low – rationality high! Really good answer!

  18. well its been awhile since i could say this, but Ole Miss beats LSU. Ole Miss 31 LSU 13. I can wear my Ole Miss clothes prouldly again. haha.

  19. Have you ever tried Google's 'Search by image feature'?? You just need to click the little blue camera on the right side of the search bar on the images page.

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  23. Il faut signaler à la ministre que discuter du classement de Shanghai n’a aucun intérêt et qu’elle ferait mieux de s’inspirer de sa prédécesseur qui s’est sorti les doigts pour réformer l’Université, qui en a bien besoin.Se reposer sur l’héritage de celui que l’on a vilipender c’est malhonnête et tout le monde le voit.

  24. good video. i also love that cleanser. one thing about that night cream in a jar. u are dead on about not putting bacteria ridden fingers/hands in the jar . however u missed another point about jars. they lose a lot of their effective ingredients when air touches them, so bottles that are air tight are much better. surprised she used a jar.

  25. gini,you are awful…ly funny sometimes!! ; ) I haven’t watched any. Frankly these pills make me sick enough without adding to the nausea of hearing all the grand plans of our unelected premier. But yes, I do hope as well, that Dix and co. take a look at this and these stories, and get on it. No more raw logs leaving that could be cut here. But remember, Christy is not about making BC better, despite the bribery of a family day..lol… shes about making sure China is happy!

  26. <3 Ã… sÃ¥ fine de ble….. Gleder gleder gleder meg til Ã¥ se resten av de! )))Du e sÃ¥ flink altsÃ¥! (sjøl om det e lett nÃ¥r modellen e sÃ¥ nydelig, hehehe!)stooor klæm t dæ

  27. Bon déjà si tu as été invité, c’est plus 1 point … Le problème de fond c’est que ça n’a pas de goût pourtant toute la communication visuelle est traitée autour de produits qui paraissent alléchant … vas comprendre !

  28. That’s a sharp way of thinking about it.

  29. published February 18, 2010, the ongoing investigation, whose team now includes members of the U.S. National Security Agency, has also discerned that the attacks may go as far back as April and that one of the Chinese

  30. I’m so glad you decided to bake some scones! And, they look delicious. I’m going to have to try adding bananas next time. The dried fruit sounds great too. Thanks so much for the mention!

  31. How delightful to meet a new gardener! Yes this is the season that we plan our work for the next garden season! Like you I research and look at magazines and eventually become overwhelmed so I just sit patiently and enjoy my world of winter wonderland!A fellow gardener and nature lover from Canada! NG

  32. I got what you mean , thankyou for putting up.Woh I am delighted to find this website through google. “Finley is going over to get a new piece of bat.” by Jerry Coleman.

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  34. sir, i am student of japanese first year. But I want to prepare for upsc with degree of japanese . i came to know that from next year it does not required to have certain main paper for appearing for upse . should i keep preparing for it ? kindly comment.

  35. That’s a smart way of thinking about it.

  36. In the complicated world we live in, it’s good to find simple solutions.

  37. dit :Oui merci à vous, vous êtes de grands hommes et resterez à jamais dans le coeur des agenais.Merci Christian, Merci Christophe ♥

  38. Tom Friedman in his New York Times column today complains about Morsi’s visit to Tehran and once again in effect claims the presidential election in Iran in 2009 was fixed so that the “democrats” in Iran lost.

  39. disse:It’s not that I want to copy your web-site, but I really like the style. Could you tell me which theme are you using? Or was it especially designed?

  40. I also give Alex Props for winning yesterday and the coaching for unleashing the playbook. I still think Kaepernick is the future of this organization. I don’t think he’s ready yet, but I think he’s profiting from sitting right now. Given the choice between the two, I’ll take the long term returns on Kaepernick over 2 amazing performances in 7 years.

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  43. You Sir/Madam are the enemy of confusion everywhere!

  44. That photo of Perry makes him look like a cross between Mo Howard and Richard Nixon. Not as funny as the first but certainly as divisive as the latter. Perry is human vermin.

  45. The ability to think like that is always a joy to behold

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  47. Call me wind because I am absolutely blown away.

  48. Dear Fred:We met the other day at the Mae Tao clinic, I was the old American with the video camera. Any chance I can come photograph your story the week of Feb 20 as I will be in the area once again.

  49. BS low – rationality high! Really good answer!

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  57. Wait, I cannot fathom it being so straightforward.

  58. Ahhh — the first photo in section three! Love it. Very nice smile that shows your personality, the violet color is better for you than the blue, the outdoors, it’s a keeper.…

  59. Unbelievable how well-written and informative this was.

  60. então ? estará lembrado que os árabes andaram por cá vários séculos ?e não deixaram só palavras começadas por al , com certeza . de leiria para baixo é só mouros :)

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  65. Could you write about Physics so I can pass Science class?

  66. Real brain power on display. Thanks for that answer!

  67. Grover Norquist Another one of those ntigovernment extremist morons, he wants to gut every social program on the planet and privatize everything so some big ass corporations can step all over us even more than they can now.Grover Norquist wants to shift the tax burden to the middle class even more, resulting in an ever-increasing gap between the rich and poor.

  68. Which came first, the problem or the solution? Luckily it doesn’t matter.

  69. , if you just do the right thing then life is easy. It seems like such a simple mantra to follow …. not sure why so many people don’t get it.“Life’s Short … Enjoy the Ride”XOXOXOXJohn Crews – BP Owner

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  74. Bah l’article sur les hommes… c’est comme je dis, ce qui est écrit s’applique aux deux. Un gars saoul fait aussi honte à une fille qu’une fille saoule peut l’être pour un gars. C’est un comportement à proscrire tout court.

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  78. Help, I’ve been informed and I can’t become ignorant.

  79. Så fine inspirasjonsbilder:) Og takk, jeg lurer på et lignende bod, men har vært redd for at formen er for retro for vår stil. Men det passer jo flott inn i andre stiler og :D Ha en flott dag!

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  81. Looks like it was fun, not quite how I remembered them, there def was no dog shows back when I went to the VW shows. I loved what your neighbours came with, so cute. Next year hopefully you'll be taking your bay!Im getting a lorry at the mo, for winter camping, I love my bay but its too cold in the winter months, you both looed lovely too, glad you got to top up your tan :)

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  83. It’s great to find an expert who can explain things so well

  84. You’ve captured this perfectly. Thanks for taking the time!

  85. zarina, I'll be at Seoul on 31 Jan – 3 Feb..perhaps we can meet?..I have sent email to you, but its okla since u're busy with ur study…anyway good luck!!!

  86. I was seriously at DefCon 5 until I saw this post.

  87. That’s a smart way of thinking about it.

  88. Well, many advertisers, despite the real threat of higher per click costs due to increased competition (oh, Google’s post didn’t go there of course  ) are happy to hear this and they should be. They can now broaden their approach to selling through AdWords. It’s the trademark holders themselves that are up in arms. The New York Times tells of a class action suit being filed in Texas due to this already happening and raising the ire of some including a company called Firepond who is at the center of the suit.

  89. Ppl like you get all the brains. I just get to say thanks for he answer.

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  91. We were just talking about this at work today… Mine are 4 years apart too & it’s perfect for us. I can’t imagine having a 2 year old & a baby. At the age of 4 they understand do much more than a 2 year old and to me it made it easier to divide my time I honestly think I would have gone crazy with a toddler & a baby. Toddlers are so unpredictable most of the time. By the age of 4 my daughter was well mannered, of course she still had her days, but they were much milder than 2 or 3.

  92. What a joy to find such clear thinking. Thanks for posting!

  93. You’ve got to be kidding me-it’s so transparently clear now!

  94. Hey, that’s powerful. Thanks for the news.

  95. That’s an intelligent answer to a difficult question xxx

  96. This piece was a lifejacket that saved me from drowning.

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  101. If I communicated I could thank you enough for this, I’d be lying.

  102. La solution? Peut-être tout simplement boycotter les commenditaires de ces dites émissions. Ou encore espérer ou demander qu’un mécène de la Capitale nous fasse cadeau d’un réseau sachant nous représenter à cent pour cent. Pourquoi pas? On est bon pour quêter des cadeaux!

  103. El curso parece genial, y a mí me ancantaría hacerlo, al ser on-line y para niños! Se adecua perfectamentea mí. En cuanto a la página web, me ha gustado mucho, por el diseño, la información que ofrece y las fotos. A ver si hay suerte!!!!

  104. Exactly! At the most basic level I’d say that psychology focuses more on the past, and NLP focuses more on the future — yet to your point, uses subtle language to influence the individuals self-evaluation process. E.g. if they are anxious, they might be asked “at what point do you decide to be anxious” (reinforcing the choice being within their control). I believe it also seeks to use the subconscious more – almost literally like ‘reprogramming’ ones perception (which obviously could be controversial in some cases). Anyway, it’s definitely an interesting subject matter! Take care!!

  105. The easiest way would be Barry Allen on a eSATA disk/thumb drive. The internal flash memory is far too small to squeeze the browser (actually the required libs) in there.

  106. Gee…so you bought YouTube with the idea of figuring out a way to sell adds? That seems to be a risky move since the total appeal of YouTube is the free content produced by the users. If I wanted to watch ads, I would turn on network TV. I think this lessens the YouTube experience and will drive away viewers just like AtomFilms and others.

  107. Yeah ! I thought you gave up the project for a while. I’m very exciting about this OS. As you know, I don’t have the level/time for helping develop it, anyway, I could help you with small usefull program when the kernel will be enough finished. Is there any possibility to access the SVN to see the code ? Will you release it using an OSI licence ?

  108. This is way more helpful than anything else I’ve looked at.

  109. Totalmente de acuerdo. Pero yo no sé quién es el tal Javier Calvo, a Reig lo conozco de oídas, a Alberto Olmos dejé de leerlo hace tiempo y el invento ése de Distrito Kafka no pienso visitarlo: así las ratas terminarán meneándosela entre ellas.

  110. What a wonderful comparison, Melody. Thank you for sharing those insights from your mothering experiences. I can’t imagine what it must be like to raise the children you do. Your life looks so much like Jesus to me.Jeanette, I know that when you show up in my life, Christ is there. Thank you for being a part of my journey.

  111. Thanks for contributing. It’s helped me understand the issues.

  112. Anyone who thinks isolationism is an answer to anything should go ask someone from Hawaii who is old enough to have lived through Pearl Harbor how good isolationism works. But not being isolationists doesn't mean we need to attempt to rebuild a sespool like Afghanastan. We didn't ask Afghanastan to harbor the terrorists who murdered 3000 of our civilians. And if I remeber, we didn't have troops in Iraq at that point of time eiteher.

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  115. I could read a book about this without finding such real-world approaches!

  116. You really found a way to make this whole process easier.

  117. Pleasing you should think of something like that

  118. That’s what we’ve all been waiting for! Great posting!

  119. Penny Arcade SUCKS!! I have been using the Penny Arcade for a while and I love it so much!! Since i am a curious person, i decided to count my total before dropping in the penny Arcades to see how actual this machine is…Guess What??! my total was totally different, they ripped me off!!

  120. A Espanha mereceu o titulo de 2010, mas tem que suar muito pra ganhar mais 04 Copas e igualar o Brasil, imagina isso? Pra igualar, é meus amigos minha seleção é foda.

  121. 1c2I will continue to shop at Target, again, even more if I don’t have to be exposed to someone breast feeding their child there. Do it in private. Thank you for posting the above email address however. I wanted to email them and let them know how offensive it is to see someone breastfeeding in public, especially when there are private places provided. Again, thank you. Target did NOTHING wrong here.

  122. Ben de mutfakta beyaz rengi seviyorum. Beyaz renk gibisi yok. Mutfakta gerçekten başka bir değer koyuyor ortaya şık havalı ve temiz gerçekten. Paylaşım için teşekkürler.

  123. Guys can you help me Yesterday I returned from the mountains and m are kiavetta brought my reconnection to back today, everything goes more and nn nn and the LED flashes back more drive than ever? I tried again it has always worked to remove and replace the hex, but how can I help more go nn!

  124. awsum Can somebody tell me if somebody else than your self can add & remove contacts in your profile of friends? waiting for help…Thankyou

  125. Unbelievable how well-written and informative this was.

  126. If you’re reading this, you’re all set, pardner!

  127. I came, I read this article, I conquered.

  128. Angeles se me hacen muchos para el tamaño de acuario que tienes. Tengo uno similar al tuyo y tengo 11 angeles. Creo que la calidad de agua de tu acuario no es la optima y por eso se estan muriendo tus angeles. Por favor leer estas guias:

  129. Hard 404 on Google today for the link «Haunted by high energy costs? Here are some easy ways to save!» The contact link on the 404page too is leading nowhere to contact anybody at Google to inform this blunder.Happy 404!Raj

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  131. It’s always a pleasure to hear from someone with expertise.

  132. What’s it take to become a sublime expounder of prose like yourself?

  133. dang it, dave. i really want to do this, but i already have lifting in the am and rowing in the pm. :S i may have to forgo the rowing just for this. we’ll see. i’d like to see if i can beat my last time on this wod… it was 12 and some change.

  134. Shiver me timbers, them’s some great information.

  135. Beautiful recipe, Mary! I so agree about putting the veggies and the meat on separate kabobs. Strangely, most people do not do this. It is not hard to figure out. They do look prettier on the skewers in different colors, but they just don't cook correctly.

  136. That’s going to make things a lot easier from here on out.

  137. Bonjour Gaëtan,Ah ! colorant pelure d’oignon, je n’y avais pas pensé… Aujourd’hui E163V (chou rouge) et E162 (betterave), c’était plus poétique.Voyez-vous, rien qu’en lisant « …dans le Valois de mon enfance », l’envie me prend de rêver. C’est très engageant.Merci cher Gaëtan et laissons notre enfance vagabonder dans notre présent pour nous livrer ses plus beaux tableaux. Nos Renoir, intemporels aussi.

  138. Merci vinvin, effectivement, ça ne laisse pas de marbre….Et je doute que cela soit un fake.Ayant moi meme coulé grace à nos amis les banquiers il y a quelques années, je comprends ce qu’il dit….ça fout les boules….

  139. Brian this brings up another point that I think is often overlooked. We know that Elohim is a God and that Jehovah is a god but what is not often mentioned is that Michel is also a God. We know this because all 3 have the Keys of creation. It is possible for one to obtain at least a lesser form of godhod without a physical body.

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  173. Yes. The footage is from season one but clips are from many episodes not just one. Through out the season really, can’t really name the ones. sorry.

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  184. Going to do a bit of a cheat – I made card for the CCT challenge but it also fits the challenge (and I think its beter than the one I made for this challenge LOL!!)Thanks for looking,Cathy xx

  185. This is what I call a "gratitude attack". They're occurring all over the place, and in my most unscientific poll I've concluded it's because of the Lord. How precious!Blessings, Kathleen

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  187. How are the views of Rodney Hide and ACT on the issue of dedicated Maori seats on the Auckland Super City council racist exactly?Isn't Racism is when you discriminate against some person because of their race as opposed to not ensuring you have guarranteed representation? ACT's views might be culturally insensitive and even against the spirit of the Treaty of Waitangi but I would hardly call them racist. If they were then the fact that Pacific Islanders and Asians are not being guarranteed representation is also racist.

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  192. Exatamente, não é exagerado. É fiel ao livro. Outra observação: A Carrie não é piromaníaca, o dom que ela tem é o da telecinésia.

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  194. Oh yes Catherine! That bit when you're galloping along, finding it hard to type quickly enough. Saying it out loud wouldn't be fast enough either. And sometimes it's rubbish, but more often than not, when it flies I think it has something important to say about the story. I like to think so anyway!Good post Nicky. Thanks!

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