Новые виды гальванических элементов и аккумуляторов

Конечно, в этом искусстве тоже есть свои мастера. Так, фирма Ray-O-Vac разработала и изготовляет плоские сухие батареи, используемые в фотоаппаратах «Полароид». Эта 9-вольтовая батарея умещается на ладони, а толщина ее всего 3 мм. Внутри батареи находятся 6 листов проводящей фольги, на одну сторону которых нанесен слой цинкового порошка, а на другую — двуокиси марганца с добавкой сажи. Между каждыми двумя электродами проложен слой сетки из синтетических нитей, пропитанный электролитом, а вся батарея надежно герметизирована.

В последнее время появилось немало новых видов гальванических элементов и аккумуляторов. К сожалению, в этой краткой рецензии невозможно рассказать о каждом из них, поэтому мы ограничимся двумя особенно интересными новинками. Уже давно делались попытки создать полностью твердотельный гальванический элемент. Дело в том, что жидкости и пастообразные растворы могут вытекать из батареи, разъедать электроды и образовывать газы. Если же заменить электролит твердым веществом, в котором ионы также могут свободно перемещаться, то получим элемент, свободный от этих недостатков. К сожалению, в обычной ионной решетке перенос ионов возможен лишь с помощью дефектов решетки: заряженный атом может перескакивать случайным образом с одной вакансии на другую. Однако при комнатной температуре дефектов в таких кристаллах обычно бывает слишком мало для того, чтобы в них могли течь достаточно большие ионные токи.

В настоящее время наиболее эффективным полностью твердотельным элементом является литиевый. Его анод изготовлен из лития, а катод — из органического соединения, содержащего иод.

 

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